During the War of 1812, saltpetre was in demand for making black powder. Workers leached cave soil, enriched by bat guano, with water in square vats to extract calcium nitrate. The solution ran through hollowed tulip-poplar logs to the surface, where it was processed with wood ash. Production declined after the war ended in 1815.
Most of the miners were enslaved African American men, some leased from nearby states. They worked in cold, dark conditions and also built early trails inside the cave. The preserved vats and scaffolding make that labor visible in the same room where it happened.